找了很久,终于给我找到!哈哈哈... 
//听说php4也已经支持Java/EJB的说. 
<? 
// this script is come from zend. :) 
$word = new COM("word.application") or die("Unable to instanciate Word 
");  
print "Loaded Word, version {$word->Version}n";  
$word->Visible = 1;  
$word->Documents->Add();  
$word->Selection->TypeText("This is a test...");  
$word->Documents[1]->SaveAs("Useless test.doc");  
$word->Quit();  
?> 
注意:先用phpinfo()看看你的机器是否打开了COM支持. 

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